If you're serious about multihulls, I'd highly recommend you pickup Chris White's The Cruising Multihull and Mike McMullen's Multihull Seamanship.
As for learning to sail... My recommendation to you is to spend your first year coastal cruising and doing progressively longer sails and working your way up to short blue water passages and then longer and longer passages.
I'd also recommend that you take at least a basic ASA 101 learn to sail course, which will give you a solid foundation to base your learning on. Better yet, take the whole sequence, including the 101, 103, 104, 105 and 106 courses, which would give you the basic fundamentals of cruising on a sailboat... along with the navigation skills you'll need.
If you want to learn how to do this yourself, the basic 101 course is a minimum IMHO, and will get you off to a fairly decent start.
I'd recommend you pick up the following books:
Dave Seidman's The Complete Sailor
Richard K. Hubbard's Boater's Bowditch
Beth Leonard's The Voyager's Handbook
Richard Henderson's Singlehanded Sailing
Don Casey's This Old Boat and Complete Illustrated Sailboat Maintenance Manual
The Annapolis Book of Seamanship or Chapman's.
This basic library will give you a basic sailing primer, a basic book on navigation techniques, a book on cruising, a book on sailing long distances singlehanded, two books on sailboat maintenance and upkeep, and a book on the rules and traditions of seamanship.
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You know what the first rule of sailing is? ...Love. You can learn all the math in the 'verse, but you take
a boat to the sea you don't love, she'll shake you off just as sure as the turning of the worlds. Love keeps
her going when she oughta fall down, tells you she's hurting 'fore she keens. Makes her a home.
—Cpt. Mal Reynolds, Serenity (edited)
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Still—DON'T READ THAT POST AGAIN.