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We had similar brown discoloration problem with epoxy filler (WEST) repairs that I made to our deck - filling in dings and cracks. That was due to UV rays degrading the epoxy, and we ended up repainting the entire deck. Fiberglass gelcoat should not have this UV problem, so there may have been a contaminant in the gelcoat mix, or as some have mentioned above, a separate spill or stain. If the mix was contaminated, you will need to grind it down and do it over.
 
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